1,2,3,4,5,6,7,8-OCTATHIONANE, A NOVEL CYCLIC POLYSULFIDE - SYNTHESIS AND CRYSTAL-STRUCTURE

被引：19

作者：

TOKITOH, N

TAKEDA, N

IMAKUBO, T

GOTO, M

OKAZAKI, R

机构：

[1] UNIV TOKYO, FAC SCI, DEPT CHEM, HONGO 7-3-1, BUNKYO KU, TOKYO 113, JAPAN

[2] NATL CHEM LAB IND, TSUKUBA, IBARAKI 305, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 08期

关键词：

D O I：

10.1246/cl.1992.1599

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermal reaction of a sterically bulky diazomethane with elemental sulfur in benzene afforded a novel cyclic polysulfide, 1,2,3,4,5,6,7,8-octathionane (1). Molecular structure of 1 was determined by X-ray crystallographic analysis and the geometry of its CS8 ring of 1 was compared with that of the theoretically optimized cyclononasulfur (S9).

引用

收藏

页码：1599 / 1602

页数：4

相关论文

共 20 条

[1] ISOTOPE EFFECTS IN MOLECULAR MECHANICS (MM2) CALCULATIONS ON DEUTERIUM COMPOUNDS [J].

ALLINGER, NL ;

FLANAGAN, HL .

JOURNAL OF COMPUTATIONAL CHEMISTRY, 1983, 4 (03) :399-403

[2] SULFURATION OF THE NORBORNENE DOUBLE-BOND [J].

BARTLETT, PD ;

GHOSH, T .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (22) :4937-4943

[3] SYNTHESIS, STRUCTURE, AND PROPERTIES OF PENTATHIEPINS [J].

CHENARD, BL ;

HARLOW, RL ;

JOHNSON, AL ;

VLADUCHICK, SA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :3871-3879

[4] VARACIN - A NOVEL BENZOPENTATHIEPIN FROM LISSOCLINUM-VAREAU THAT IS CYTOTOXIC TOWARD A HUMAN COLON-TUMOR [J].

DAVIDSON, BS ;

MOLINSKI, TF ;

BARROWS, LR ;

IRELAND, CM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (12) :4709-4710

[5] SPORIDESMINS .12. ISOLATION AND STRUCTURE OF SPORIDESMIN-G, A NATURALLY-OCCURRING 3,6-EPITETRATHIOPIPERAZINE-2,5-DIONE [J].

FRANCIS, E ;

TAYLOR, A ;

SAFE, S ;

RAHMAN, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1972, (04) :470-&

[6] STRUCTURE OF SULFUR CLUSTERS USING SIMULATED ANNEALING - S-2 TO S-13 [J].

HOHL, D ;

JONES, RO ;

CAR, R ;

PARRINELLO, M .

JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (11) :6823-6835

[7] FLUORINATED CYCLIC POLYSULFIDES AND THEIR POLYMERS [J].

KRESPAN, CG ;

BRASEN, WR .

JOURNAL OF ORGANIC CHEMISTRY, 1962, 27 (11) :3995-&

[8] ELEMENTAL SULFUR [J].

MEYER, B .

CHEMICAL REVIEWS, 1976, 76 (03) :367-388

[9]

MORITA K, 1967, CHEM PHARM BULL, V15, P988

[10] 2,4,6-TRIS(BIS(TRIMETHYLSILYL)METHYL)PHENYL, A NEW STERICALLY DEMANDING GROUP FOR KINETIC STABILIZATION OF UNSTABLE COMPOUNDS [J].

OKAZAKI, R ;

UNNO, M ;

INAMOTO, N .

CHEMISTRY LETTERS, 1987, (11) :2293-2294