HYDROLYSIS KINETICS OF DILUTE AQUEOUS CHROMIUM(3) PERCHLORATE

被引：20

作者：

RICH, LD

COLE, DL

EYRING, EM

机构：

[1] Department of Chemistry, University of Utah, Salt Lake City

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 03期

关键词：

D O I：

10.1021/j100723a037

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dissociation field effect relaxation times in dilute aqueous chromium(III) perchlorate solutions have been measured and attributed to the hydrolysis equilibrium (Equation Presented) At 25° the specific rate k-1≅ 7.8 × 108 M-1 sec-1 at an ionic strength μ≅ 5 × 10-4 M. This k-1 is approximately six times smaller than that measured previously for reaction between a proton and AlOH2+.

引用

页码：713 / &

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