GLOW DISCHARGE POLYMERIZATION .2. ALPHA-METHYLSTYRENE, OMEGA-METHYLSTYRENE AND ALLYLBENZENE

被引：41

作者：

DENARO, AR

OWENS, PA

CRAWSHAW, A

机构：

[1] Department of Chemistry and Biology, Liverpool Regional College of Technology, Liverpool, England

来源：

EUROPEAN POLYMER JOURNAL | 1969年 / 5卷 / 04期

关键词：

D O I：

10.1016/0014-3057(69)90076-7

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Previous work on the deposition of polymer on the electrodes of a radiofrequency glow discharge through styrene vapour has been extended to the examination of three other monomers. The mechanism proposed for styrene involving the competitive reactions of radicals formed on the electrodes by electron bombardment, is applicable to the other monomers but it now appears that the radical recombination reaction can be neglected. It is not yet clear whether the propagation step involves the reaction of radicals with adsorbed monomer or with monomer diffusing to the electrode from the gas phase. © 1969.

引用

页码：471 / &

共 11 条

[1]

BRANDRUP J, 1966, POLYMER HANDBOOK

[2]

Chapiro A., 1962, RAD CHEM POLYM SYSTE, P446

[3] THE POLYMERIZATION OF ALLYLBENZENE WITH HETEROGENEOUS CATALYSTS [J].

DALELIO, GF ;

FINESTONE, AB ;

TAFT, L ;

MIRANDA, TJ .

JOURNAL OF POLYMER SCIENCE, 1960, 45 (145) :83-89

[4] POLYMERIZATION OF ALLYLBENZENE WITH LEWIS ACIDS - A POLYALKYLATION REACTION [J].

DAVIDSON, EB .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1966, 4 (3PB) :175-&

[5] GLOW DISCHARGE POLYMERIZATION-STYRENE [J].

DENARO, AR ;

OWENS, PA ;

CRAWSHAW, A .

EUROPEAN POLYMER JOURNAL, 1968, 4 (01) :93-+

[6]

FRANCIS G, 1960, IONIZATION PHENOMENA, pCH4

[7] IRRADIATION OF POLYMERS BY HIGH-ENERGY ELECTRONS [J].

LAWTON, EJ ;

BUECHE, AM ;

BALWIT, JS .

NATURE, 1953, 172 (4367) :76-77

[8]

LEVINA RY, 1934, J GEN CHEM USSR, V4, P1250

[9] EFFECT OF CHEMICAL STRUCTURE OF VINYL POLYMERS ON CROSSLINKING AND DEGRADATION BY IONIZING RADIATION [J].

MILLER, AA ;

LAWTON, EJ ;

BALWIT, JS .

JOURNAL OF POLYMER SCIENCE, 1954, 14 (77) :503-504

[10] LIGHT SCATTERING AND VISCOSITY STUDY OF ELECTRON-IRRADIATED POLYSTYRENE AND POLYMETHACRYLATES [J].

SHULTZ, AR ;

ROTH, PI ;

RATHMANN, GB .

JOURNAL OF POLYMER SCIENCE, 1956, 22 (102) :495-507

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