SYNTHESIS OF MONOLIGATE DITERTIARY PHOSPHINO COMPLEXES OF NIOBIUM(IV) CHLORIDE AND THEIR BONDING INTERACTION WITH MO(CO)(6)

被引：0

作者：

SHARMA, S

SONIKA

GUPTA, S

VERMANI, OP

NARULA, AK

机构：

[1] KURUKSHETRA UNIV, DEPT CHEM, KURUKSHETRA 132119, HARYANA, INDIA

[2] REG ENGN COLL, KURUKSHETRA, HARYANA, INDIA

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1995年 / 34卷 / 11期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reduction of niobium chloride with aluminium or zinc in the presence of various ditertiary phosphines give biligate complexes of the type [N-2,Cl-8(P P over arc)(2)], while sodium amalgam reduction of NbCl5 give monoligate complexes of the type [Nb2Cl8(P P over arc)(4)]. The complex [Nb2Cl8(dppe)(4)] on further treatment with Mo(CO)(6) yielded heteronuclear bimetallic complex [Nb2Cl8(P P over arc)(4)Mo-2(CO)(8)]. The complexes have been characterized by elemental analysis, IR and NMR spectral studies.

引用

页码：883 / 887

页数：5

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