ESR INVESTIGATION OF SINGLE-CRYSTAL OF (BU4N)(2)[CU/PD(DMIT)(2)]

被引：0

作者：

QI, F ^{[1
]}

HAN, SY ^{[1
]}

LEI, H ^{[1
]}

SUI, YX ^{[1
]}

YOU, XZ ^{[1
]}

机构：

[1] NANJING UNIV,INST COORDINAT CHEM,CTR MAT ANAL,NANJING 210008,PEOPLES R CHINA

来源：

SCIENCE IN CHINA SERIES B-CHEMISTRY | 1994年 / 37卷 / 06期

关键词：

CU-DMIT COMPLEX; SINGLE-CRYSTAL ESR; G AND A TENSORS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By incorporating (Bu(4)N)(2)[Cu(dmit)(2)] with the diamagnetic host complex (Bu(4)N)(2)[Pd (dmit)(2)], single crystal of (Bu(4)N)(2)[Cu/Pd(dmit)(2)] is obtained. Its ESR spectra of various orientations are recorded. The principal values of g and A tensors and their direction cosines are computed using a least-squares fitting procedure, and based on which the molecular orbital of unpaired electron in [Cu(dmit)(2)](2-) is described. The essence of the two magnetically non-equivalent sites is also revealed.

引用

页码：653 / 659

页数：7

共 10 条

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