CENTENARY LECTURE - THE PURSUIT OF SELECTIVITY IN RADICAL REACTIONS

被引：134

作者：

BECKWITH, ALJ

机构：

[1] Research School of Chemistry, Australian National University, Canberra, ACT 2601, Australia

[2] Department of Chemistry, Research School of Chemistry, Australian National University (ANU), Canberra, ACT, Australia

[3] University of Western Australia

[4] Oxford University

[5] CSIRO, Melbourne, Vic., Australia

[6] University of Adelaide

[7] Organic Chemistry Department

[8] ANU

[9] Imperial College London

[10] University of York

[11] Australian Academy of Science

[12] Royal Society

来源：

CHEMICAL SOCIETY REVIEWS | 1993年 / 22卷 / 03期

关键词：

D O I：

10.1039/cs9932200143

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The recognition of the factors which influence the chemo-, regio-, and stereo-selectivity of organic free radical reactions has underpinned recent developments in the application of such reactions to the synthesis of complex molecules. In this review the role of thermochemical, stereoelectronic, steric, and polar effects in determining selectivity will be discussed and illustrated with examples drawn mainly from recent work carried out at the Australian National University.

引用

页码：143 / 151

页数：9

共 69 条

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ADLINGTON RM, 1990, MOLECULAR MECHANISMS IN BIOORGANIC PROCESSES, P1

[2]

BALDWIN JE, 1989, RECENT ADV CHEM BETA, P1

[3] OXYGEN CARBON BETA-BOND EFFECTS IN RADICAL REACTIONS [J].