INTRAMOLECULAR INTERACTION OF PORPHYRIN MOIETIES IN 2,5-PIPERAZINEDIONE-BRIDGED PORPHYRIN DIMERS

被引：52

作者：

TAMIAKI, H ^{[1
]}

SUZUKI, S ^{[1
]}

MARUYAMA, K ^{[1
]}

机构：

[1] KYOTO UNIV, FAC SCI, DEPT CHEM, KYOTO 60601, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 09期

关键词：

D O I：

10.1246/bcsj.66.2633

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Diastereomerically pure 2,5-piperazinedione-bridged meso-tetraarylporphyrin dimers were synthesized with easy procedures. H-1 NMR, UV-vis, and CD spectra showed that porphyrin moieties in the L,L-molecule interacted more strongly than those in the D,L-isomer and this interaction decreased with substitution by 3,5-di-t-butyl groups on the meso-phenyl substituents.

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页码：2633 / 2637

页数：5

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