ELECTRONIC SPECTRA OF BINUCLEAR MOLYBDENUM(2) CARBOXYLATES

被引：54
作者：
DUBICKI, L
MARTIN, RL
机构：
[1] Department of Inorganic Chemistry, University of Melbourne, Parkville, VIC
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 08期
关键词：
D O I：
10.1071/CH9691571
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The electronic spectra of binuclear molybdenum(II) acetate, benzoate, p-fluorobenzoate, and pentafluorobutyrate show intense absorption at ≃ 30000cm-1 which may, in part, be due to strong Mo-Mo bonding. The binuclear structure is characterized by a weak band at ≃ 23000 cm-1 which displays extensive vibrational fine structure. A semi-empirical molecular orbital calculation is used as an aid in the interpretation of the spectra. © 1969, CSIRO. All rights reserved.
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页码：1571 / &
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