AROMATICITY OF MULTIPLY-CHARGED FULLERENE IONS

被引：26
|
作者：
AIHARA, J [1 ]
HOSOYA, H [1 ]
机构：
[1] OCHANOMIZU UNIV, FAC SCI, DEPT INFORMAT SCI, TOKYO 112, JAPAN
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 07期
关键词：
D O I：
10.1246/bcsj.66.1955
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The topological resonance energies (TREs) indicate that mono- to hexaanions of C60 are as aromatic as the neutral species. The tendency of multiply charged C60 anions to retain their own spherical conjugated systems can be attributed to aromatic character. Tetraanions of C28, C36, and C44 are likewise predicted to be highly aromatic. Thus, the formation of metallofullerenes, such as U@C28, U@C36, and U@C44, can be rationalized in terms of aromaticities of the ligands.
引用
收藏
页码：1955 / 1958
页数：4
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