HYDROGEN-BONDING IN POLYBENZIMIDAZOLE POLY(ETHER IMIDE) BLENDS - A SPECTROSCOPIC STUDY

被引：92
作者：
MUSTO, P [1 ]
KARASZ, FE [1 ]
MACKNIGHT, WJ [1 ]
机构：
[1] UNIV MASSACHUSETTS,DEPT POLYMER SCI & ENGN,AMHERST,MA 01003
来源：
MACROMOLECULES | 1991年 / 24卷 / 17期
关键词：
D O I：
10.1021/ma00017a006
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A systematic investigation by FTIR spectroscopy of the blend system consisting of the polybenzimidazole poly[2,2'-(m-phenylene)-5,5'-bibenzimidazole] (PBI) and the poly(ethe imide) poly[2,2-bis[4-(3,4-dicarboxyphenoxy)phenyl]propane-m-phenylenediimine] (Ultem 1000) has been undertaken. Direct evidence of hydrogen bonding involving the N-H groups of PBI and the imide carbonyls of Ultem 1000 is presented. Qualitative as well as quantitative information concerning this molecular interaction has been obtained and is discussed. Finally an FTIR-temperature study of this quasi-miscible system is reported: by monitoring the frequency of the asymmetric stretching vibration of the imide carbonyls as a function of temperature, information has been derived on the phase separation process for various blend compositions.
引用
收藏
页码：4762 / 4769
页数：8
相关论文
共 50 条
[31]   Local Structure and Dynamics of Water Absorbed in Poly(ether imide): A Hydrogen Bonding Anatomy [J].
de Nicola, Antonio ;
Correa, Andrea ;
Milano, Giuseppe ;
La Manna, Pietro ;
Musto, Pellegrino ;
Mensitieri, Giuseppe ;
Scherillo, Giuseppe .
JOURNAL OF PHYSICAL CHEMISTRY B, 2017, 121 (14) :3162-3176
[32]   Miscibility and tensile properties of poly (phthalazinone ether ketonexetone)/poly(ether imide) blends [J].
Liao, GX ;
Jian, XG ;
Jin, QF ;
He, W ;
Wu, LH ;
Li, QA .
ACTA POLYMERICA SINICA, 2002, (03) :394-397
[33]   A STUDY OF HYDROGEN-BONDING BETWEEN DIMETHYL ETHER AND HYDROGEN HALIDES IN SOLID PHASE [J].
SEEL, RM ;
SHEPPARD, N .
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1969, A 25 (07) :1287-&
[34]   Phase behaviour of ternary blends of poly(ethylene naphthalate), poly(ether imide) and poly(ether ether ketone) [J].
Bicakci, S ;
Cakmak, M .
POLYMER, 1998, 39 (17) :4001-4010
[35]   MISCIBILITY OF POLY(ETHER IMIDE) POLY(ETHYLENE-TEREPHTHALATE) BLENDS [J].
JO, WH ;
LEE, MR ;
MIN, BG ;
LEE, MS .
POLYMER BULLETIN, 1994, 33 (01) :113-118
[36]   INFRARED AND ULTRAVIOLET SPECTROSCOPIC STUDY OF HYDROGEN-BONDING IN SOME TETRAHYDRONAPHTHOLS [J].
LAHA, S ;
CHATTERJEE, K ;
CHAKRAVORTI, S ;
GANGULY, T ;
BANERJEE, SB .
CHEMICAL PHYSICS LETTERS, 1982, 91 (06) :511-514
[37]   SPECTROSCOPIC STUDY OF PROTON-TRANSFER AND DYNAMICS OF HYDROGEN-BONDING [J].
DENISOV, GS ;
GOLUBEV, NS ;
SCHREIBER, VM .
STUDIA BIOPHYSICA, 1976, 57 :25-30
[38]   Crystallization kinetics of poly(trimethylene terephthalate)/poly(ether imide) blends [J].
Chiu, HJ ;
Shu, WJ ;
Huang, JM .
POLYMER ENGINEERING AND SCIENCE, 2006, 46 (01) :89-96
[39]   Miscibility studies on a poly (ether imide) and poly (methyl methacrylate) blends [J].
Cakar, F. ;
Yazici, O. ;
Adli, E. .
OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS, 2016, 10 (7-8) :578-582
[40]   A COMPARISON OF MODELS FOR HYDROGEN-BONDING IN POLYMER BLENDS [J].
PAINTER, PC ;
VEYTSMAN, B ;
COLEMAN, MM .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1994, 32 (06) :1189-1193
12345