MASS-SPECTRAL STUDY OF THE PYROLYSIS OF TETRAKIS(TRIFLUOROMETHYL)ALLENE

被引：0

作者：

KAGRAMANOV, ND

KUTIN, AA

机构：

[1] N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1990年 / 39卷 / 11期

关键词：

D O I：

10.1007/BF00958868

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Low-energy mass spectrometry and chromato-mass spectrometry have been used to show that major final products of the pyrolysis of tetrakis(trifluoromethyl) allene (TTA) are perfluoro-1,3-cyclopentadiene and hexafluoroethane, formed as a result of the thermal loss of two trifluoromethyl radicals. This indicates the lack of an interaction of the trifluoromethyl substituents with the cumulene bond pi-electrons.

引用

页码：2408 / 2410

页数：3

共 11 条

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