INFRARED STUDIES OF ETHENE HYDROGENATION OVER ZRO2

被引：21

作者：

DOMEN, K

KONDO, J

MARUYA, K

ONISHI, T

机构：

[1] Research Laboratory of Resources Utilization, Tokyo Institute of Technology, Yokohama, 227, 4259 Nagatsuta, Midori-ku

来源：

CATALYSIS LETTERS | 1992年 / 12卷 / 1-3期

关键词：

ETHENE; HYDROGENATION; IR SPECTROSCOPY; ZRO2;

D O I：

10.1007/BF00767195

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydrogenation of adsorbed ethene over ZrO2 at low temperature was observed by in situ infrared transmission spectroscopy. It was found that di-hydrogen was directly activated on the site where ethene was already adsorbed, which was confirmed by the comparison of adsorbed species produced during the reaction and adsorbed ethane species.

引用

页码：127 / 138

页数：12

共 28 条

[1] HYDROGENATION OF OLEFINS ON ALUMINA .I. ACTIVE SITES FOR HYDROGENATION OF ETHYLENE [J].

AMENOMIYA, Y ;

CHENIER, JHB ;

CVETANOVIC, RJ .

JOURNAL OF CATALYSIS, 1967, 9 (01) :28-+

[2] ETHYLENE HYDROGENATION MECHANISM ON THE PT(111) SURFACE - THEORETICAL DETERMINATION [J].

ANDERSON, AB ;

CHOE, SJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (16) :6145-6149

[3] AN INSITU INFRARED SPECTROSCOPIC INVESTIGATION OF THE ROLE OF ETHYLIDYNE IN THE ETHYLENE HYDROGENATION REACTION ON PD/AL2O3 [J].

BEEBE, TP ;

YATES, JT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (04) :663-671

[4] REACTIONS BETWEEN HYDROCARBONS AND DEUTERIUM ON CHROMIUM OXIDE GEL .1. GENERAL [J].

BURWELL, RL ;

LITTLEWOOD, AB ;

CARDEW, M ;

PASS, G ;

STODDART, CTH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (24) :6272-6280

[5] REACTIONS BETWEEN HYDROCARBONS AND DEUTERIUM ON CHROMIUM OXIDE GEL .5. STEREOCHEMISTRY [J].

CARDEW, M ;

BURWELL, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (24) :6289-6291

[6] CATALYSIS OF ADDITION OF DEUTERIUM TO ETHYLENE OVER ZINC OXIDE [J].

CONNER, WC ;

INNES, RA ;

KOKES, RJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (24) :6858-&

[7] EVIDENCE FOR INTERMEDIATES DURING HYDROGENATION OVER ZINC OXIDE [J].

DENT, AL ;

KOKES, RJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (25) :7207-&

[8] HYDROGENATION OF ETHYLENE BY ZINC OXIDE .I. ROLE OF SLOW HYDROGEN CHEMISORPTION [J].

DENT, AL ;

KOKES, RJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1969, 73 (11) :3772-&

[9] INTERMEDIATES IN ETHYLENE HYDROGENATION OVER ZINC OXIDE [J].

DENT, AL ;

KOKES, RJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1970, 74 (20) :3653-&

[10] HYDROGENATION OF ETHYLENE BY ZINC OXIDE .2. MECHANISM AND ACTIVE SITES [J].

DENT, AL ;

KOKES, RJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1969, 73 (11) :3781-&

← 1 2 3 →