REACTIONS OF DICYCLOPENTADIENYLTITANIUM(III) COMPOUNDS WITH CARBON-MONOXIDE

被引：32

作者：

DEBOER, EJM ^{[1
]}

CATE, LCT ^{[1
]}

STARING, AGJ ^{[1
]}

TEUBEN, JH ^{[1
]}

机构：

[1] UNIV GRONINGEN, ANORGAN CHEM LAB, NL-9747 AG GRONINGEN, NETHERLANDS

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 181卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)85737-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of Cp2TiR (R = Cl, C6F5, C6H5, o-CH3C6H4) with CO give two types of products: terminally coordinated adducts, Cp2Ti(R)CO, and insertion products, Cp2TiCOR, i.e. acyl compounds. The acyl ligand is η2-coordinated at the titanium atom. The preparations and properties of the compounds are described. © 1979.

引用

页码：61 / 68

页数：8

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