STUDIES IN THE TRICYCLOOCTANE SERIES .I. DEHYDROHALOGENATION OF SOME BIS-HALOGENOCARBENE ADDUCTS OF CYCLOHEXADIENES

被引：25

作者：

BANWELL, MG ^{[1
]}

HALTON, B ^{[1
]}

机构：

[1] VICTORIA UNIV WELLINGTON,DEPT CHEM,WELLINGTON,NEW ZEALAND

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1979年 / 32卷 / 04期

关键词：

D O I：

10.1071/CH9790849

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction between 4, 4, 8, 8-tetrachloro-cis-transoid-cis-tricyclo[5, l, 0, 03, 5]octane (1d) and potassium t-butoxide leads to the (E)- and (Z)-β-t-butoxy-4-chlorostyrenes (8a, b). The epimeric 4, 4, 8-trichloro analogues (1e, f) behave similarly to give (E)-β-t-butoxystyrene (8c) as the sole isolable product in low yield. Under the same conditions the corresponding tri- and tetra-chloro-cis-transoid-cis-tricyclo[5, 1, 0, 02, 4]octanes (7d-f) yield complex product mixtures. Evidence is presented which suggests the non-involvement of halogenocyclooctatetraenes in these reactions. © 1979, CSIRO. All rights reserved.

引用

页码：849 / 858

页数：10

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