FLUORIDE-ION ATTACK TOWARDS TRIAZINES

被引：3

作者：

LORK, E

CHEN, SJ

KNITTER, G

MEWS, R

机构：

[1] Institut für Anorganische und Physikalische Chemie der Universität Bremen, Bremen, Leobener Straße NW2, Postfach 330440

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 93卷 / 1-4期

关键词：

D O I：

10.1080/10426509408021842

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

From the reaction of TAS-fluoride (Me(2)N)(3)S(+)Me(3)SiF(2)(-)(1) and fluorotriazines (FCN)(n)(FSN)(3-n) (n = 1-3) and sulfanuric fluoride (FS(O)N)(3) stable salts with the anions [(F2CN)(FCN)(n-1)(FSN)(3-n)](-) and [(NS(O)F)(3)F](-) are isolated. Interaction with P3N3F6 gives (TAS(+))(2) P3N3F5NPF2NPF2NPF52-, a cyclic-acyclic dianion. From the addition of F- to CF2- CF2-N = S = N cyclic bis(imino)fluorosulfinate is formed, from S4N4 and 1 TAS(+) S3N3- is obtained.

引用

页码：309 / 311

页数：3

共 7 条

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