FLUORIDE-ION ATTACK TOWARDS TRIAZINES

被引：3
作者：
LORK, E
CHEN, SJ
KNITTER, G
MEWS, R
机构：
[1] Institut für Anorganische und Physikalische Chemie der Universität Bremen, Bremen, Leobener Straße NW2, Postfach 330440
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 93卷 / 1-4期
关键词：
D O I：
10.1080/10426509408021842
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
From the reaction of TAS-fluoride (Me(2)N)(3)S(+)Me(3)SiF(2)(-)(1) and fluorotriazines (FCN)(n)(FSN)(3-n) (n = 1-3) and sulfanuric fluoride (FS(O)N)(3) stable salts with the anions [(F2CN)(FCN)(n-1)(FSN)(3-n)](-) and [(NS(O)F)(3)F](-) are isolated. Interaction with P3N3F6 gives (TAS(+))(2) P3N3F5NPF2NPF2NPF52-, a cyclic-acyclic dianion. From the addition of F- to CF2- CF2-N = S = N cyclic bis(imino)fluorosulfinate is formed, from S4N4 and 1 TAS(+) S3N3- is obtained.
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页码：309 / 311
页数：3
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