6,8-Dihydroxy-8a-methyl-3,5-dimethylidenedecahydronaphtho[2,3-b]furan-2(3H)-one

被引:1
作者
Liu, Ting-Ting [1 ]
Wu, Hai-Bo [1 ]
Wang, Wen-Shu [1 ]
机构
[1] Minzu Univ China, Coll Life & Environm Sci, Beijing 100081, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词
data-to-parameter ratio = 10.8; mean ̄(C-C) = 0.003 Å; R factor = 0.047; single-crystal X-ray study; T = 133 K; wR factor = 0.124;
D O I
10.1107/S160053681204425X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, C15H20O4, is a eudesmanolide isolated from the Chinese medicinal plant Carpesium triste Maxim. The molecule contains three rings, viz. two fused six-membered rings in chair conformations and a five-membered ring in a flattened envelope conformation. In the crystal, two hydroxy groups are involved in the formation of intra-and intermolecular O-H center dot center dot center dot O hydrogen bonds. The H atoms in these groups are split, with site-occupation factors of 0.5. The intermolecular hydrogen bonds link molecules into chains propagating in [010].
引用
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页码:O3251 / +
页数:7
相关论文
共 3 条
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  • [2] Masao M, 1975, PHYTOCHEMISTRY, V14, P2247
  • [3] A short history of SHELX
    Sheldrick, George M.
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122