CRYSTAL-STRUCTURE OF THE COMPOUND LI3ZN0.5GEO4

被引：25

作者：

PLATTNER, E

VOLLENKLE, H

机构：

[1] Institut für Mineralogie, Kristallographie und Strukturchemie, Technische Universität Wien, Wien

来源：

MONATSHEFTE FUR CHEMIE | 1979年 / 110卷 / 03期

关键词：

Crystal structure; Germanate; lithium zinc-; Lithium zinc germanate;

D O I：

10.1007/BF00938373

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of the compound Li3Zn0.5GeO4 has been determined and refined by means of three-dimensional Fourier syntheses and least squares. Li3Zn0.5GeO4 crystallizes orthorhombic with space group D2h16-Pmnb (No. 62) and the lattice parameters a=6.29, b=10.74 and c=5.17 Å. The crystal structure consists of isolated [GeO4] tetrahedra, which are linked together by [(Li,Zn)O4] tetrahedra analogous to Li3PO4(h). An additional eight-fold position is partly occupied by two lithium atoms. The occupancy of this position may vary according to the observed range of composition, which lies between Li3.8Zn0.1GeO4 and Li2.6Zn0.7GeO4. © 1979 Springer-Verlag.

引用

页码：693 / 698

页数：6

共 6 条

[1]

MONNAYE B, 1976, REV CHIM MINER, V13, P422

[2] CRYSTAL-STRUCTURE OF COMPOUND LI2ZNGEO4 [J].