A SYNTHETIC ENTRY INTO AZASEMIBULLVALENE SYSTEM . UNSATURATED HETEROCYCLIC SYSTEMS .62.

被引：32

作者：

PAQUETTE, LA

KROW, GR

机构：

[1] Department of Chemistry, Ohio State University, Columbus

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 22期

关键词：

D O I：

10.1021/ja01050a030

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of an azasemibullvalene derivative has been accomplished in three steps commencing with theaddition of chlorosulfonyl isocyanate to hexamethyl (Dewarbenzene) (5). The stereochemistry of electrophilic addition to 5 is discussed. A rearrangement of lactam 11 is described. © 1969, American Chemical Society. All rights reserved.

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页码：6107 / &

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