A NEW SERIES OF ORGANOLANTHANIDES - LN(INDENYL)3

被引：56

作者：

TSUTSUI, M

GYSLING, HJ

机构：

[1] Department of Chemistry, New York University, Bronx

[2] Department of Chemistry, Texas A&M University, College Station

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 12期

关键词：

D O I：

10.1021/ja01040a013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new series of organolanthanides containing the indenyl group and having the general formula Ln(C9H7)3•OC4H8 (Ln = La, Sm, Gd, Tb, Dy, and Yb) has been prepared by the reaction of the corresponding anhydrous trichloride with sodium indenide in tetrahydrofuran solution. The magnetic properties of these derivatives have been studied, and in the cases of the diamagnetic La and the weakly paramagnetic Sm compounds proton nmr spectra have been recorded. Evidence is presented for a covalent bonding mode in the Sm derivative. © 1969, American Chemical Society. All rights reserved.

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页码：3175 / &

相关论文

共 22 条

[1] THE CYCLOPENTADIENIDES OF SCANDIUM, YTTRIUM AND SOME RARE EARTH ELEMENTS [J].

BIRMINGHAM, JM ;

WILKINSON, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (01) :42-44

[2]

BURMEISTER JL, 1967, 10 P INT C COORD CHE, P356

[3] STEREOCHEMICALLY NONRIGID ORGANOMETALLIC MOLECULES .8. FURTHER STUDIES OF SIGMA-CYCLOPENTADIENYLMETAL COMPOUNDS [J].

COTTON, FA ;

MUSCO, A ;

YAGUPSKY, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (24) :6136-&

[4] A NEW TYPE OF INTRAMOLECULAR ANTIFERROMAGNETISM [J].

FEISTEL, GR ;

MATHAI, TP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (11) :2988-+

[5] UBER DICYCLOPENTADIENYLEUROPIUM UND DICYCLOPENTADIENYLYTTERBIUM UND TRICYCLOPENTADIENYLE DES TERBIUMS HOLMIUMS THULIUMS UND LUTETIUMS [J].

FISCHER, EO ;

FISCHER, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1965, 3 (03) :181-&

[6] COMPLEXES OF TRICYCLOPENTADIENYL-LANTHANIDES WITH BASES [J].

FISCHER, EO ;

FISCHER, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1966, 6 (02) :141-&

[7] INNERE ELEKTRONENANREGUNGEN VON TRICYCLOPENTADIENYL-KOMPLEXEN DES YTTERBIUMS [J].

FISCHER, RD ;

FISCHER, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1965, 4 (05) :412-&

[8] ON BEHAVIOUR OF F-ELECTRONS INFLUENCED BY UNUSUAL LIGANDS FIELD .2. ABSORPTION SPECTRUM OF TRICYCLOPENTADIENYLTHULIUM [J].

FISCHER, RD ;

FISCHER, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1967, 8 (01) :155-&

[9] SPEKTROSKOPISCHE UNTERSUCHUNGEN AN ORGANOMETALLISCHEN VERBINDUNGEN .20. SUSZEPTIBILITATSBESTIMMUNGEN PARAMAGNETISCHER STOFFE AUS KERNRESONANZ-MESSUNGEN [J].

FRITZ, HP ;

SCHWARZHANS, KE .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1964, 1 (03) :208-211

[10] ORGANOMETALLIC COMPOUNDS OF TITANIUM, ZIRCONIUM, AND LANTHANUM [J].

GILMAN, H ;

JONES, RG .

JOURNAL OF ORGANIC CHEMISTRY, 1945, 10 (06) :505-515