2-PHOTON ABSORPTION AND 3RD-HARMONIC GENERATION OF DI-ALKYL-AMINO-NITRO-STILBENE (DANS) - A JOINT EXPERIMENTAL AND THEORETICAL-STUDY

被引：87
作者：
BELJONNE, D
BREDAS, JL
CHA, M
TORRUELLAS, WE
STEGEMAN, GI
HOFSTRAAT, JW
HORSTHUIS, WHG
MOHLMANN, GR
机构：
[1] PUSAN NATL UNIV,DIELECT & ADV MATTER PHYS RES CTR,PUSAN 609735,SOUTH KOREA
[2] UNIV CENT FLORIDA,CTR RES ELECTROOPT & LASERS,ORLANDO,FL 32826
[3] AKZO CORP,NOBEL CENT RES,6800 SB ARNHEM,NETHERLANDS
来源：
JOURNAL OF CHEMICAL PHYSICS | 1995年 / 103卷 / 18期
关键词：
D O I：
10.1063/1.470200
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The one- and two-photon optical absorption spectra as well as the frequency dependent third-harmonic generation response of a side-chain polymer containing 4-dialkylamino-4'-nitro-stilbene (DANS) as its side group have been measured over a wide range of frequency. A three-state model, based on an intermediate neglect of differential overlap/multireference double-configuration interaction description of the excited states, provides a coherent picture of the dynamic response of DANS, but fails in reproducing the red shift observed when going from the linear to the nonlinear absorption spectra; including vibronic coupling within the Franck-Condon approximation improves the fit. (C) 1995 American Institute of Physics.
引用
收藏
页码：7834 / 7843
页数：10
相关论文
共 38 条
  • [1] TUNABLE 3RD HARMONIC-GENERATION OF TRANS-BETA-CAROTENE
    ARAMAKI, S
    TORRUELLAS, W
    ZANONI, R
    STEGEMAN, GI
    [J]. OPTICS COMMUNICATIONS, 1991, 85 (5-6) : 527 - 535
  • [2] BELJONNE D, UNPUB J PHYS CHEM
  • [3] 3RD-ORDER NONLINEAR-OPTICAL RESPONSE IN ORGANIC MATERIALS - THEORETICAL AND EXPERIMENTAL ASPECTS
    BREDAS, JL
    ADANT, C
    TACKX, P
    PERSOONS, A
    PIERCE, BM
    [J]. CHEMICAL REVIEWS, 1994, 94 (01) : 243 - 278
  • [4] BREDAS JL, 1990, NATO ARW E, V182
  • [5] INDIVIDUALIZED CONFIGURATION SELECTION IN CI CALCULATIONS WITH SUBSEQUENT ENERGY EXTRAPOLATION
    BUENKER, RJ
    PEYERIMH.SD
    [J]. THEORETICA CHIMICA ACTA, 1974, 35 (01): : 33 - 58
  • [6] THE 2(1)A(G) STATE OF ISOLATED CIS,TRANS-1,3,5,7-OCTATETRAENE - 2-COLOR RESONANCE ENHANCED 2-PHOTON IONIZATION STUDIES
    BUMA, WJ
    KOHLER, BE
    SHALER, TA
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (01) : 399 - 407
  • [7] 2-PHOTON ABSORPTION OF DI-ALKYL-AMINO-NITRO-STILBENE SIDE-CHAIN POLYMER
    CHA, M
    TORRUELLAS, WE
    STEGEMAN, GI
    HORSTHUIS, WHG
    MOHLMANN, GR
    METH, J
    [J]. APPLIED PHYSICS LETTERS, 1994, 65 (21) : 2648 - 2650
  • [8] CHA MC, UNPUB
  • [9] Chemia D. S., 1987, NONLINEAR OPTICAL PR
  • [10] EXPERIMENTAL INVESTIGATIONS OF ORGANIC MOLECULAR NONLINEAR OPTICAL POLARIZABILITIES .1. METHODS AND RESULTS ON BENZENE AND STILBENE DERIVATIVES
    CHENG, LT
    TAM, W
    STEVENSON, SH
    MEREDITH, GR
    RIKKEN, G
    MARDER, SR
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (26) : 10631 - 10643
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