BEHAVIORS OF MIXED SOLUTES IN SURFACTANT ADMICELLES

被引:3
作者
LEE, C
TSAI, H
机构
[1] Department of Marine Environment, National Sun Yat-Sen University, Kaohsiung Taiwan
关键词
D O I
10.1080/01496399508015839
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Binary adsolubilizations of hexanol, phenol, and cyclohexanol in admicelles formed by sodium dodecylsulfate on aluminum oxide were studied. Calculations from the phase equilibrium model give sizable synergism of adsolubilizations in the presence of other solutes. In this work, however, all solutes behaved ideally up to a moderate adsorption density in all binary experiments. It is concluded that further modifications are necessary before these equilibrium calculations can be used to describe the effect of background solutes. Furthermore, significant deviations from ideal behavior in binary experiments due to competition adsolubilization were observed as the capacity of admicelles oversaturated.
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页码:285 / 300
页数:16
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