Bis[2-(benzyliminomethyl)pyrrol-1-ido-kappa N-2,N ']bis(dimethylamido-kappa N)-titanium(IV)

被引：0

作者：

Chen, Zhou ^{[1
]}

Liu, Yonglu ^{[2
]}

Li, Yahong ^{[1
,2
]}

Hu, Bin ^{[1
]}

机构：

[1] Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China

[2] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

D O I：

10.1107/S1600536812014365

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The mononuclear title complex, [Ti(C2H6N)(2)(C12H11N2)(2)], was synthesized by the reaction of 1-phenyl-N-[(pyrrol-2-yl)methylidene]methanamine with Ti(NMe2)(4). The Ti-IV atom is coordinated in a distorted octahedral geometry by four N atoms from two derivatized methanamine ligands and two N atoms from two dimethylamide ions. The dihedral angles between the pyrrole and phenyl rings in the bidentate ligands are 62.36 (9) and 78.32 (8)degrees. In the crystal, a weak pi-pi stacking interaction [centroid-centroid distance = 3.864 (2) angstrom] involving centrosymmetrically related molecules is observed.

引用

页码：M573 / +

页数：8

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