KINETICS OF FESO4 SONOLYTIC OXIDATION IN AQUEOUS-SOLUTIONS

被引：0
|
作者：
IONESCU, SG [1 ]
POPA, N [1 ]
机构：
[1] FAC CHEM BUCHAREST,DEPT INORGAN CHEM,BUCHAREST,ROMANIA
来源：
REVUE ROUMAINE DE CHIMIE | 1992年 / 37卷 / 07期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The kinetics of Fe(II)SO4 sonolytic oxidation in aqueous solutions at pH = 1-2, in the concentration range 1.5 X 10(-3) - 1.5 X 10(-2)M was studied. A reaction mechanism was proposed, based on the strong oxidizing efect of OH radicals generated in H2O primary sonolysis. The effect to Fe(II)SO4 concentration on the oxidation rate constant was consistent with Noyes' scavenging kinetics of OH radicals, providing similarities with some thermal and photochemical reactions involving such reactive intermediates.
引用
收藏
页码：747 / 753
页数：7
相关论文
共 50 条
  • [1] KINETICS OF IODINE SONOLYTIC GENERATION IN POTASSIUM-IODIDE AQUEOUS-SOLUTIONS
    POPA, N
    IONESCU, SG
    REVUE ROUMAINE DE CHIMIE, 1989, 34 (07) : 1561 - 1564
  • [2] KINETICS OF ENZYMATIC OXIDATION IN FREEZED AQUEOUS-SOLUTIONS
    SERGEEV, GB
    BATYUK, VA
    SERGEEV, BM
    DOKLADY AKADEMII NAUK SSSR, 1974, 214 (06): : 1354 - 1357
  • [3] KINETICS OF LIGNIN OXIDATION BY OZONE IN AQUEOUS-SOLUTIONS
    BENKO, EM
    KOVALEVA, VV
    MITROFANOVA, AN
    VOBLIKOVA, VA
    PRYAKHIIN, AN
    LUNIN, VV
    ZHURNAL FIZICHESKOI KHIMII, 1994, 68 (09): : 1580 - 1583
  • [4] KINETICS OF BIOMACROMOLECULE RADIATION OXIDATION AND PHOTOOXIDATION IN AQUEOUS-SOLUTIONS
    SAPEZHINSKII, II
    USPEKHI KHIMII, 1985, 54 (09) : 1559 - 1579
  • [5] KINETICS OF OXIDATION OF VANADIUM(III) BY BROMINE IN AQUEOUS-SOLUTIONS
    ADEGITE, A
    FORDSMIT.MH
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (19): : 2113 - &
  • [6] KINETICS OF CHEMICAL AND BIOLOGICAL SULFIDE OXIDATION IN AQUEOUS-SOLUTIONS
    BUISMAN, C
    IJSPEERT, P
    JANSSEN, A
    LETTINGA, G
    WATER RESEARCH, 1990, 24 (05) : 667 - 671
  • [7] KINETICS OF OXIDATION OF CU(I) BY OXYGEN IN AQUEOUS-SOLUTIONS
    RUBIO, FC
    DUENAS, MPP
    CARRETERO, JM
    ANALES DE QUIMICA SERIE A-QUIMICA FISICA Y QUIMICA TECNICA, 1987, 83 (02): : 200 - 205
  • [8] CONSISTENCY OF FESO4 DOSIMETRY
    LAW, J
    PHYSICS IN MEDICINE AND BIOLOGY, 1970, 15 (02): : 301 - &
  • [9] INTERCOMPARISONS OF FESO4 DOSEMETER SOLUTIONS, AND USE OF SUCH SOLUTIONS FOR A POSTAL DOSIMETRY SERVICE
    AHMED, SA
    LAW, J
    WALTON, PW
    PHYSICS IN MEDICINE AND BIOLOGY, 1970, 15 (01): : 135 - &
  • [10] Leaching kinetics of low nickel matte in an aqueous solution of sulfuric acid saturated with FeSO4 and NiSO4
    Xiao, Wanhai
    Li, Yongli
    Zhao, Zhongwei
    Liu, Xuheng
    SEPARATION AND PURIFICATION TECHNOLOGY, 2021, 276
12345