STUDIES OF THE REACTIONS OF MOLECULAR FLUORINE WITH METHANE, ACETYLENE, ETHYLENE, ALLENE, AND OTHER SMALL HYDROCARBONS IN MATRICES AT LOW-TEMPERATURES

被引：34

作者：

HAUGE, RH ^{[1
]}

GRANSDEN, S ^{[1
]}

WANG, JLF ^{[1
]}

MARGRAVE, JL ^{[1
]}

机构：

[1] RICE UNIV,DEPT CHEM,HOUSTON,TX 77001

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 23期

关键词：

D O I：

10.1021/ja00517a027

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of molecular fluorine with small hydrocarbons were studied in fluorine and argon-fluorine matrices. Certain hydrocarbons (methane, acetylene, benzene, ethane, etc.) could be condensed into a pure fluorine matrix without reaction. Ethylene and allene could also be condensed in fluorine without reaction, but did react when exposed to light in the wavelength region from 1 to 4 μ. The ethylene reaction produced either 1,2-gauche-and trans-difluoroethane or vinyl fluoride and hydrogen fluoride. Propylene, butadiene, and cyclohexene reacted (spontaneously) with molecular fluorine in low-temperature matrices. © 1979, American Chemical Society. All rights reserved.

引用

页码：6950 / 6954

页数：5

共 8 条

[1]

BADACHHAPE RB, 1979, KIRK OTHMER ENCYCLOP

[2] ELIMINATION OF HF FROM HOT FLUORINATED ETHANES . AN ESTIMATION OF ACTIVATION ENERGIES AND RATE PARAMETERS [J].