ORGANOMETALLIC COMPLEXES FOR NONLINEAR OPTICS .4. CUBIC HYPERPOLARIZABILITIES OF (CYCLOPENTADIENYL)BIS(PHOSPHINE)RUTHENIUM SIGMA-ARYLACETYLIDES

被引：68

作者：

WHITTALL, IR

HUMPHREY, MG

机构：

[1] AUSTRALIAN NATL UNIV,DEPT CHEM,CANBERRA,ACT 0200,AUSTRALIA

[2] AUSTRALIAN NATL UNIV,RES SCH PHYS SCI & ENGN,CTR LASER PHYS,CANBERRA,ACT 0200,AUSTRALIA

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 12期

关键词：

D O I：

10.1021/om00012a015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Third-order molecular optical nonlinearities of a systematically varied series of (cyclopentadienyl) bis(phosphine)ruthenium arylacetylide complexes have been determined by Z-scan and degenerate four-wave mixing techniques: the influence on the nonlinear response of replacing the acetylide by a chloro ligand, varying the phosphine, extending the acetylide chain length, or modifying the substituent at the 4-position of the arylacetylide has been studied.

引用

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页码：5493 / 5495

页数：3

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