COBALT(II) COMPLEXES OF SOME SEMICARBAZONES AND THIOSEMICARBAZONES

被引：29

作者：

KUMAR, A ^{[1
]}

USHA ^{[1
]}

CHANDRA, S ^{[1
]}

机构：

[1] ZAKIR HUSAIN COLL, DEPT CHEM, JL NEHRU MARG, NEW DELHI 110002, INDIA

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1993年 / 23卷 / 04期

关键词：

D O I：

10.1080/15533179308016665

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cobalt(II) complexes of semicarbazones and thiosemicarbazones of 2-hydroxyacetophenone, 2-hydroxynaphthaldehyde, 4-hydroxyacetophenone and 3-methyl-2-butanone have been synthesised and characterised. The complexes of semicarbazones and thiosemicarbazones of 2-hydroxyacetophenone and 2-hydroxynaphthaldehyde were found to have the general composition [Co(ligand)2], while the complexes of 3-methyl-2-butanone and 4-hydroxyacetophenone have the composition [Co(ligand)2X2], X - Cl, Br, NO3, SO4 and CH3COO. Possible geometries of the complexes were assigned on the basis of magnetic moments, IR, electronic and ESR spectral studies.

引用

页码：671 / 684

页数：14

共 33 条

[1]

ABLOV AV, 1964, ZH NEORG KHIM+, V9, P85

[2] STRUCTURAL ASPECTS OF CO-ORDINATED NITRATE GROUPS [J].

ADDISON, CC ;

LOGAN, N ;

WALLWORK, SC ;

GARNER, CD .

QUARTERLY REVIEWS, 1971, 25 (02) :289-&

[3]

ALI MA, 1974, COORDIN CHEM REV, V13, P101

[4]

BEKHEIT MM, 1990, B SOC CHIM FR, P153

[5] COMPLEXES WITH SULFUR AND SELENIUM DONOR LIGANDS .5. SOME CO(II) COMPLEXES WITH BIDENTATE AND MONODENTATE UNSUBSTITUTED THIOSEMICARBAZONES [J].

BELLITTO, C ;

TOMLINSON, AAG ;

FURLANI, C ;

DEMUNNO, G .

INORGANICA CHIMICA ACTA, 1978, 27 (02) :269-274

[6]

BLANZ EJ, 1970, J MED CHEM, V13, P1124

[7] INFRARED SPECTRA OF SOME URANYL NITRATE COMPLEXES [J].

BULLOCK, JI .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1967, 29 (09) :2257-&

[8] INFRARED SPECTRAL STUDY OF PENTACO-ORDINATED COBALT(II) COMPLEXES OF THIOSEMICARBAZONES [J].

CAMPBELL, MJM ;

GRZESKOWIAK, R ;

THOMAS, R ;

GOLDSTEIN, M .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1976, 32 (03) :553-557

[9] TRANSITION-METAL COMPLEXES OF THIOSEMICARBAZIDE AND THIOSEMICARBAZONES [J].

CAMPBELL, MJM .

COORDINATION CHEMISTRY REVIEWS, 1975, 15 (2-3) :279-319

[10] SULPHUR-NITROGEN CHELATING AGENTS .6. 5-COORDINATE AND 6-COORDINATE COMPLEXES OF 3D METAL IONS WITH AN SNN TRIDENTATE LIGAND [J].

CHIA, PSK ;

LIVINGST.SE .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1969, 22 (08) :1613-&

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