RUTHENIUM COMPLEX-CATALYZED ALLYLIC ALKYLATION OF CARBONUCLEOPHILES WITH ALLYLIC CARBONATES

被引：107

作者：

ZHANG, SW ^{[1
]}

MITSUDO, T ^{[1
]}

KONDO, T ^{[1
]}

WATANABE, Y ^{[1
]}

机构：

[1] KYOTO UNIV,FAC ENGN,DEPT HYDROCARBON CHEM,SAKYO KU,KYOTO 60601,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 450卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80158-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Allylic carbonates except for allyl methyl carbonate reacted with carbonucleophiles such as ethyl acetoacetate in the presence of a catalytic amount of Ru(cod)(cot) [cod = cycloocta-1,5-diene, cot = cycloocta-1,3,5-triene] in N-methylpiperidine at 80-degrees-C to give the corresponding monoallylated carbonucleophiles in high yields with high regioselectivity. The regioselectivity was quite different from that in the palladium-catalyzed reactions. The allylation of carbonucleophiles using allyl methyl carbonate selectively gave the diallylated carbonucleophiles in high yields.

引用

页码：197 / 207

页数：11

共 30 条

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