STRUCTURE AND SPECTROSCOPIC PROPERTIES OF [(2,6-PH2C6H3O)2TI(MU-CL)2TI(OC6H3PH2-2,6)2] - EVIDENCE FOR A STRONG METAL METAL INTERACTION

被引：24

作者：

HILL, JE ^{[1
]}

NASH, JM ^{[1
]}

FANWICK, PE ^{[1
]}

ROTHWELL, IP ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

POLYHEDRON | 1990年 / 9卷 / 13期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0277-5387(00)86582-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The compound [(2,6-Ph2C6H3O)2Ti(μ-Cl)2Ti(OC6H3Ph2-2,6)2] which is formed by sodium amalgam reduction of Ti(OC6H3Ph2-2,6)2Cl2 (OC6H3Ph2-2,6 = 2,6-diphenylphenoxide) contains a relatively short TiTi distance of 2.9827(7) Å and acute Ti(μ-Cl)Ti angles of 77.79(3) and 78.05(3)°. Crystal data at -130°C: space group P1; a = 13.342(4), b = 13.808(4), c = 16.057(3) Å, α = 97.35(2), β = 104.63(2), γ = 91.64(2)°, Z = 2; ρ{variant}calc = 1.346 g cm-3. © 1990.

引用

页码：1617 / 1619

页数：3

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