S4N4 AND ITS DERIVATIVES - STRUCTURE OF THE REACTION-PRODUCT FROM NI(HN2S2)2, FORMALDEHYDE, AND METHANOL

被引：7

作者：

THEWALT, U

机构：

[1] Sektion f. Röntgen- und Elektronenbeugung d. Univ, Ulm

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1979年 / 451卷 / APR期

关键词：

D O I：

10.1002/zaac.19794510118

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Eine Röntgenstrukturanalyse ergibt, daß der Nickel(II)‐Komplex NiC2H6N4OS4, der bei der Umsetzung von Ni(HN2S2)2 mit Formaldehyd in Methanol entsteht, die struktur D besitzt. Die beiden ebenen NiN2S2‐Ringe sind nahezu parallel. Im Kristall sind die Ni(N2S2)2‐Bereiche der Moleküle parallel gepackt. Die Kristalle sind monoklin, Raumgruppe P1 mit a = 8,433(5), b = 8,610(4), c = 7,716(5) Å, α = 114,64(6), β = 75,16(5), γ = 112.51(4)° and Z = 2. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim

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页码：123 / 128

页数：6

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