S4N4 AND ITS DERIVATIVES - STRUCTURE OF THE REACTION-PRODUCT FROM NI(HN2S2)2, FORMALDEHYDE, AND METHANOL

被引：7
作者：
THEWALT, U
机构：
[1] Sektion f. Röntgen- und Elektronenbeugung d. Univ, Ulm
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1979年 / 451卷 / APR期
关键词：
D O I：
10.1002/zaac.19794510118
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Eine Röntgenstrukturanalyse ergibt, daß der Nickel(II)‐Komplex NiC2H6N4OS4, der bei der Umsetzung von Ni(HN2S2)2 mit Formaldehyd in Methanol entsteht, die struktur D besitzt. Die beiden ebenen NiN2S2‐Ringe sind nahezu parallel. Im Kristall sind die Ni(N2S2)2‐Bereiche der Moleküle parallel gepackt. Die Kristalle sind monoklin, Raumgruppe P1 mit a = 8,433(5), b = 8,610(4), c = 7,716(5) Å, α = 114,64(6), β = 75,16(5), γ = 112.51(4)° and Z = 2. Copyright © 1979 Verlag GmbH & Co. KGaA, Weinheim
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页码：123 / 128
页数：6
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