ISOTHERMAL VAPOR-LIQUID-EQUILIBRIA OF MIXTURES CONTAINING ORGANIC-COMPOUNDS .7. EXCESS GIBBS ENERGIES OF CHLOROALKANE + OXAALKANE MIXTURES AT 298.15-K

被引：5
作者：
LEPORI, L
MATTEOLI, E
TINE, MR
机构：
[1] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,VIA RISORGIMENTO 35,I-56126 PISA,ITALY
[2] CNR,IST CHIM QUANTIST & ENERGET MOLEC,I-56126 PISA,ITALY
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1991年 / 36卷 / 04期
关键词：
D O I：
10.1021/je00004a018
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Vapor-liquid equilibria for a chloroalkane (1,2-dichloroethane or 1,1,1-trichloroethane) + a linear mono- or diether (diethyl ether, dipropyl ether, methyl butyl ether, 1,2-dimethoxyethane) or an acetal (diethoxymethane), were determined at 298.15 K by head-space gas chromatographic analysis of the vapor phase directly withdrawn from an equilibration apparatus. Excess Gibbs energies, activity coefficients at infinite dilution, and free energies of solvation were calculated for all the systems.
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页码：406 / 409
页数：4
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