CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(PYRIDINE)N,N'-O-PHENYLEN-BIS[2-CYAN-2-ETHOXYCARBONYL-VINYL-AMIDO(-)]-IRON(II)-PYRIDINE

被引：11

作者：

GORLS, H ^{[1
]}

JAGER, EG ^{[1
]}

机构：

[1] UNIV JENA,FAK CHEM,O-6900 JENA,GERMANY

来源：

CRYSTAL RESEARCH AND TECHNOLOGY | 1991年 / 26卷 / 03期

关键词：

D O I：

10.1002/crat.2170260319

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal and molecular structure of bis(pyridine)N,N'-o-phenylen-bis[2-cyan-2-ethoxycarbonyl-vinyl-amido(-)]iron(II)-pyridine were determined by X-ray structure analysis. It crystallizes in the monoclinic space group P2(1)/c with cell parameters a = 9.866(23), b = 19.491(46), c = 16.992(22) angstrom, and beta = 95.19(1)-degrees. The structure was solved by the heavy atom method and refined to R = 0.125. The coordination geometry around the iron atom is octahedrally distorted with the two pyridine molecules in the axial positions.

引用

页码：349 / 355

页数：7

共 13 条

[1]

CLEGG W, 1978, PLUTO 78 PROGRAM PLO

[2]

COPPENS P, 1985, ACTA CRYSTALLOGR C, V41, P902

[3] STRUCTURE OF HEXAPYRIDINEIRON(2) SALT OF TETRANUCLEAR IRON CARBONYL ANION[FE4(CO)13]-2 WITH COMMENTS CONCERNING NONISOLATION OF CORRESPONDING NEUTRAL TETRANUCLEAR IRON CARBONYL FE4(CO)14 [J].