FRACTALS AND RELATED HIERARCHICAL-MODELS IN POLYMER SCIENCE

被引:39
作者
BLUMEN, A [1 ]
SCHNORER, H [1 ]
机构
[1] BAYREUTHER INST MAKROMOLEK FORSCH, W-8580 BAYREUTH, GERMANY
关键词
Fractals; Polymers; Theoretical chemistry;
D O I
10.1002/anie.199001133
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polymer science, an interdisciplinary science well‐rooted in organic chemistry and in materials science, encompasses an inordinate number and diversity of substance classes and thus has far‐reaching applications. Interestingly, polymers also represent a great challenge to the theoreticians, since their theoretical treatment often necessitates appropriate extensions of the classical methods from solid state physics and from statistical physics. Thus, new concepts often have to be invoked when considering the special properties of polymers. In this review we concentrate on one of the modern concepts in the theory of polymers, namely on scaling. Scaling is closely associated with new developments in the field of fractals and of hierarchical structures. Such concepts are invaluable for the modeling of complex geometries and for describing dynamical processes in polymeric materials. Here, we focus on a presentation of these ideas and we outline examples of recent research in which these concepts have been successfully applied. Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany
引用
收藏
页码:113 / 125
页数:13
相关论文
共 116 条
[11]  
[Anonymous], 1971, MODERN THEORY POLYM
[12]  
[Anonymous], 1979, SCALING CONCEPTS POL
[13]   The electrical resistivity log as an aid in determining some reservoir characteristics [J].
Archie, GE .
TRANSACTIONS OF THE AMERICAN INSTITUTE OF MINING AND METALLURGICAL ENGINEERS, 1942, 146 :54-61
[14]   CHEMISTRY IN NONINTEGER DIMENSIONS BETWEEN 2 AND 3 .2. FRACTAL SURFACES OF ADSORBENTS [J].
AVNIR, D ;
FARIN, D ;
PFEIFER, P .
JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (07) :3566-3571
[15]  
Avnir D., 1989, FRACTAL APPROACH HET
[16]  
Bachelier L., 1900, ANN SCIENTIFIQUES LE, V17, P21, DOI DOI 10.24033/ASENS.476
[17]   PHOTON-HARVESTING POLYMERS - SINGLET ENERGY-TRANSFER IN ANTHRACENE-LOADED ALTERNATING AND RANDOM COPOLYMERS OF 2-VINYLNAPHTHALENE AND METHACRYLIC-ACID [J].
BAI, F ;
CHANG, CH ;
WEBBER, SE .
MACROMOLECULES, 1986, 19 (10) :2484-2494
[18]   EXCITATION TRANSFER IN DISORDERED TWO-DIMENSIONAL AND ANISOTROPIC 3-DIMENSIONAL SYSTEMS - EFFECTS OF SPATIAL GEOMETRY ON TIME-RESOLVED OBSERVABLES [J].
BAUMANN, J ;
FAYER, MD .
JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (07) :4087-4107
[19]   INFLUENCE OF RESTRICTED GEOMETRIES ON THE DIRECT ENERGY-TRANSFER [J].
BLUMEN, A ;
KLAFTER, J ;
ZUMOFEN, G .
JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (03) :1397-1401
[20]  
BLUMEN A, 1988, NATO ASI SER C, V235, P21