Long-range interatomic dipoles

被引：16

作者：

Brown, W. Byers ^{[1
]}

Whisnant, D. M. ^{[1
]}

机构：

[1] Univ Wisconsin, Inst Theoret Chem, Madison, WI 53706 USA

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 7卷 / 03期

关键词：

D O I：

10.1016/0009-2614(70)80174-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new formula is presented for the coefficient D-7 of the leading term in R-7 for the electric dipole moment of two atoms in S-states at a large distance R apart. An approximation is proposed which leads to a simple formula for D-7 involving mainly accessible atomic properties. The approximation is checked for scaled hydrogen atoms and is accurate to about one per cent.

引用

页码：329 / 332

页数：4

共 22 条

[1]

BOSOMWORTH DR, 1965, CAN J PHYS, V43, P752

[2]

BUCKINGHAM AD, 1959, PROPRIETES OPTIQUES, P57

[3] THEORY OF LONG-RANGE INTERATOMIC FORCES .1. DISPERSION ENERGIES BETWEEN UNEXCITED ATOMS [J].

FONTANA, PR .

PHYSICAL REVIEW, 1961, 123 (05) :1865-&

[4] COLLISION-INDUCED ABSORPTION AS A PROBE OF RARE-GAS INTERATOMIC POTENTIALS [J].

FUTRELLE, RP .

PHYSICAL REVIEW LETTERS, 1967, 19 (09) :479-&

[5] THEORY OF DIPOLE MOMENTS INDUCED BETWEEN WELL-SEPARATED ATOMS [J].

GERSTEN, JI .

PHYSICAL REVIEW, 1969, 179 (01) :1-&

[6] LONG-RANGE INTERACTION OF 2 LS-HYDROGEN ATOMS EXPRESSED IN TERMS OF NATURAL SPIN-ORBITALS [J].

HIRSCHFELDER, JO ;

LOWDIN, PO .

MOLECULAR PHYSICS, 1959, 2 (03) :229-258

[7] CORRECTIONS [J].

HIRSCHFELDER, JO .

MOLECULAR PHYSICS, 1965, 9 (05) :491-+

[8] VAN DER WAALS FORCES IN ATOMS AND MOLECULES [J].

KARPLUS, M ;

KOLKER, HJ .

JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (12) :3955-&

[9] PRESSURE-INDUCED INFRARED ABSORPTION OF MIXTURES OF RARE GASES [J].

KISS, ZJ ;

WELSH, HL .

PHYSICAL REVIEW LETTERS, 1959, 2 (04) :166-168

[10]

Kolos W., 1967, International Journal of Quantum Chemistry, V1, P169, DOI 10.1002/qua.560010206

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