CHARACTERIZATION OF PYROLYSIS CONDITIONS AND INTERFERENCE BY OTHER COMPOUNDS IN THE CHEMI-LUMINESCENCE DETECTION OF NITROSAMINES

被引：30

作者：

HANSEN, TJ ^{[1
]}

ARCHER, MC ^{[1
]}

TANNENBAUM, SR ^{[1
]}

机构：

[1] MIT,DEPT NUTR & FOOD SCI,CAMBRIDGE,MA 02139

来源：

ANALYTICAL CHEMISTRY | 1979年 / 51卷 / 09期

关键词：

D O I：

10.1021/ac50045a038

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Facile analysis of N-nitroso compounds has been made possible by the development of chemiluminescence detectors. Response of one such detector as a function of pyrolysis chamber temperature has been characterized for several nitrosamines and for an aliphatic C-nitro compound, an aromatic C-nitro compound, a nitramine, an alkylnitrite, and a nitrosourea. The response-temperature profiles are valuable in distinguishing among the various compounds and in optimizing the sensitivity of the detector for use in chromatography. Other tests, including photolysis and stability toward nitrite-scavenging reagents, further aid in distinguishing among the various compounds. © 1979, American Chemical Society. All rights reserved.

引用

页码：1526 / 1528

页数：3

共 25 条

[1] STUDIES IN THE HYDROLYSIS AND ALCOHOLYSIS OF SOME ORGANIC NITRITES [J].