CYCLOADDITIONS OF HEXACHLOROCYCLOPENTADIENE TO 7-SUBSTITUTED NORBORNADIENES - REMOTE SUBSTITUENT EFFECTS ON REACTIVITY AND STEREOSELECTIVITY

被引：13

作者：

HOUK, KN

MUELLER, PH

WU, YD

MAZZOCCHI, PH

SHOOK, D

KHACHIK, F

机构：

[1] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90024

[2] UNIV MARYLAND,DEPT CHEM,COLLEGE PK,MD 20742

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 50期

关键词：

D O I：

10.1016/S0040-4039(00)88545-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rates and stereoselectivities of the cycloadditions of hexachlorocyclopentadiene to norbornadienes substituted at the 7-position by tert-butyl, trimethylsilyl, methoxy, acetoxy, hydroxy, methoxymethyl, and methoxycarbonyl groups have been measured. The rates correlate with subsfituent electronegativities. © 1990.

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页码：7285 / 7288

页数：4

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