FORMATION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS BY PALLADIUM-CATALYZED OXIDATION OF ALLYLIC ALCOHOLS

被引：49
作者：
GOMEZBENGOA, E
NOHEDA, P
ECHAVARREN, AM
机构：
[1] UNIV AUTONOMA MADRID,DEPT QUIM ORGAN,E-28049 MADRID,SPAIN
[2] CSIC,INST QUIM ORGAN,E-28006 MADRID,SPAIN
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 38期
关键词：
D O I：
10.1016/0040-4039(94)88235-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Treatment of allylic alcohols with catalytic amounts of palladium catalysts in the presence of oxygen leads to the formation of alpha,beta-unsaturated carbonyl compounds.
引用
收藏
页码：7097 / 7098
页数：2
相关论文
共 18 条
[1]   STEREOSELECTIVE PALLADIUM CATALYZED CYCLIZATION ON CARBOHYDRATE TEMPLATES - A ROUTE TO CHIRAL CYCLOPENTANES AND SOME HETEROCYCLIC-ANALOGS [J].
ENGELBRECHT, GJ ;
HOLZAPFEL, CW .
TETRAHEDRON LETTERS, 1991, 32 (19) :2161-2164
[2]  
GODLESKI SA, 1991, COMPREHENSIVE ORGANI, V4
[3]   ALKYLPALLADIUM(II) SPECIES - REACTIVE INTERMEDIATES IN A BIS-CYCLIZATION ROUTE TO STRAINED POLYFUSED RING-SYSTEMS [J].
GRIGG, R ;
SRIDHARAN, V ;
SUKIRTHALINGAM, S .
TETRAHEDRON LETTERS, 1991, 32 (31) :3855-3858
[4]   A PALLADIUM-MEDIATED APPROACH TO CONSTRUCTION OF NITROGEN-HETEROCYCLES [J].
HARRIS, GD ;
HERR, RJ ;
WEINREB, SM .
JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (09) :2528-2530
[5]  
Heck R. F., 1985, PALLADIUM REAGENTS O
[6]  
HERTZ W, 1968, J ORG CHEM, V33, P3743
[7]   SYNTHESIS OF [5.5.5.5]FENESTRANES BY PD-CATALYZED CARBONYLATION-CYCLIZATION [J].
KEESE, R ;
GUIDETTIGREPT, R ;
HERZOG, B .
TETRAHEDRON LETTERS, 1992, 33 (09) :1207-1210
[8]   REGIOSELECTIVE PHOTO-OXIDATION OF ETA-3-ALLYLPALLADIUM - ACCESS TO GAMMA-FUNCTIONALIZED ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS [J].
MUZART, J ;
PALE, P ;
PETE, JP .
TETRAHEDRON LETTERS, 1983, 24 (42) :4567-4568
[9]   OXYGENATION UNDER UV-LIGHT OF ALLYLSILANES CATALYZED BY PALLADIUM(II) AND OF (ETA(3)-ALLYL)PALLADIUM COMPLEXES - A MECHANISTIC APPROACH [J].
MUZART, J ;
RIAHI, A .
ORGANOMETALLICS, 1992, 11 (10) :3478-3481
[10]  
MUZART J, 1981, J CHEM SOC CHEM COMM, P688
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