FACILE REDUCTION OF A DIALKYL ZIRCONIUM(IV) OCTAETHYLPORPHYRIN (OEP) COMPLEX BY H-2 - CRYSTAL-STRUCTURE AND SPECTROSCOPIC CHARACTERIZATION OF [(OEP)ZRCH2SIME(3)]

被引：53

作者：

BRAND, H ^{[1
]}

ARNOLD, J ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 01期

关键词：

D O I：

10.1002/anie.199400951

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The unusual stability of [(OEP)ZrCH2SiMe3] (1), which formally contains a ZrIII center and is formed by reaction of [(OEP)Zr(CH2SiMe3)2] with H2, is best explained by considering two resonance structures, a ZrIII metal‐based radical and a zwitterionic porphyrin radical anion. OEP (octaethylporphyrin) is denoted by a circle in the formulas shown on the right. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：95 / 97

页数：3

共 26 条

[1] NOVEL SYNTHETIC ROUTE TO SCANDIUM PORPHYRIN DERIVATIVES AND THE 1ST STRUCTURALLY CHARACTERIZED METALLOPORPHYRIN-ETA-5-CYCLOPENTADIENYL SANDWICH COMPOUND [J].