THERMOANALYTICAL CHARACTERIZATION OF ALEKSINAC (YUGOSLAVIA) OIL-SHALE KEROGEN

被引:8
作者
VUCELIC, D
KRSMANOVIC, VD
VUCELIC, V
KICANOVIC, M
VITOROVIC, D
机构
[1] INST CHEM TECHNOL & MET, BELGRADE, YUGOSLAVIA
[2] INST GEN & PHYS CHEM, BELGRADE, YUGOSLAVIA
关键词
D O I
10.1007/BF01913643
中图分类号
O414.1 [热力学];
学科分类号
摘要
The chemical nature of the kerogen from Aleksinac (Yugoslavia) oil shale was studied by thermal analysis of a kerogen concentrate and the partially degraded kerogen concentrates obtained as intermediates in its stepwise alkaline permanganate oxidation. The initial kerogen concentrate decomposed in the range 200-550-degrees-C and the DTG profile consisted of several overlapping peaks. The partially degraded kerogen concentrates were thermally more stable. Their thermograms consisted of two distinct parts: the low- (150-420-degrees-C) and the high-temperature (420-650-degrees-C) part. Each of them was complex, involving two or more components. On the basis of IR data, it was suggested that the low-temperature part corresponded to the thermal degradation of aliphatic, and the high-temperature part to the degradation of aromatic components.
引用
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页码:2465 / 2473
页数:9
相关论文
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