PREPARATION OF DIMETHYL CARBONATE FROM METHANOL AND CARBON-DIOXIDE IN THE PRESENCE OF ORGANOTIN COMPOUNDS

被引：72

作者：

KIZLINK, J

PASTUCHA, I

机构：

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1994年 / 59卷 / 09期

关键词：

D O I：

10.1135/cccc19942116

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dibutyltin dialkoxides react with methanol and carbon dioxide to give dimethyl carbonate in 60 to 220 mole % yields with respect to the organotin compound. The higher yields of the carbonate (150 up to 330 mole %) have been achieved with the use of chemical scavengers of the reaction water.

引用

页码：2116 / 2118

页数：3

共 4 条

[1]

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[2] SYNTHESIS OF DIMETHYL CARBONATE FROM CARBON-DIOXIDE AND METHANOL IN THE PRESENCE OF ORGANOTIN COMPOUNDS [J].

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COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1993, 58 (06) :1399-1402

[3]

Poller R.C, 1986, INTRO ORGANOMETALLIC

[4] POLYMERS DERIVED FROM CARBON-DIOXIDE AND CARBONATES [J].

YAMAZAKI, N ;

NAKAHAMA, S ;

HIGASHI, F .

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1979, 18 (04) :249-252

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