Crystal structure of (OC)(5)W(mu-dppe) W(CO)(5)

被引：0

作者：

Drake, Hannah F. ^{[1
]}

Wheeler, Kraig A. ^{[2
]}

Bellott, Brian J. ^{[1
]}

机构：

[1] Western Illinois Univ, Dept Chem, Macomb, IL 61455 USA

[2] Eastern Illinois Univ, Dept Chem, Charleston, IL 61920 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷

基金：

美国国家科学基金会;

关键词：

crystal structure; group; 6; carbonyl; bridging dppe; bimetallic;

D O I：

10.1107/S2056989016013670

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The centrosymmetric title complex, [mu-ethane-1,2-diylbis(diphenylphosphane)-kappa P-2: P '] bis[pentacarbonyltungsten(0)], [W2(C26H24P2)(CO) 10], consists of two W(CO)(5) moieties bridged by a bis(diphenylphosphanyl) ethane (dppe) ligand. The W-0 atom has a slightly distorted octahedral coordination environment consisting of 5 carbonyl ligands and one P atom from the bridging dppe ligand with the nearest W-0 atom 5.625 (5) angstrom away. The complex resides on a center of symmetry.

引用

页码：1383 / +

页数：8

共 50 条

[41] Imine coordinated 2-aminoazole complexes of (CO)5Cr(0) and (CO)5W(0), verification by structural characterisation [J].

de Jongh, Leigh-Anne ;

Strasser, Christoph E. ;

Raubenheimer, Helgard G. ;

Cronje, Stephanie .

POLYHEDRON, 2009, 28 (16) :3635-3641

[42] Reactions of (THF) W(CO)(5) with some diphosphenes carrying bulky aryl and phenoxy groups [J].

An, DL ;

Toyota, K ;

Yasunami, M ;

Yoshifuji, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 508 (1-2) :7-12

[43] THE STRUCTURE OF [CO-2(CO)(5)(MU(2),ETA(4)-CPHCHCHCPH)] A COBALT ANALOG OF THE FERROLES [J].

MOLDES, I ;

PAPWORTH, T ;

ROS, J ;

ALVAREZLARENA, A ;

PINIELLA, JF .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 489 (1-2) :C65-C67

[44] ORGANOMETALLIC OXIDES - THE CRYSTAL-STRUCTURE OF [(ETA-C5H5)TI](8)(MU-O)(12) [J].

HESHMATPOUR, F ;

WOCADLO, S ;

MASSA, W ;

DEHNICKE, K ;

BOTTOMLEY, F ;

DAY, RW .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (06) :827-830

[45] Reactions of metal-metal triply bonded complexes [(η5-RC5H4)2M2(CO)4] (M = Mo, W) with diphenyl ditelluride.: Crystal structures of [(η5-MeC5H4)Mo2(CO)4(μ-TePh)3] and [(η5-EtO2CC5H4)2W2(CO)4(μ-TePh)2] [J].

Song, LC ;

Shi, YC ;

Hu, QM ;

Chen, Y ;

Sun, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 626 (1-2) :192-198

[46] NEW FE-MO AND FE-W FULVALENE-BRIDGED HETEROBIMETALLIC COMPLEXES CONTAINING THE FERROCENYL UNIT - CRYSTAL-STRUCTURE OF [(ETA-C5H5)FE(MU-ETA-ETA-C(5)H(4)IND) MO(CO)(2)(ETA-C3H5)] (IND=1-INDENYL) [J].

WAN, S ;

BEGLEY, MJ ;

MOUNTFORD, P .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 489 (1-2) :C28-C31

[47] High-entropy silicide superconductors with W5Si3-type structure [J].

Liu, Bin ;

Yang, Wuzhang ;

Xiao, Guorui ;

Zhu, Qinqing ;

Song, Shijie ;

Cao, Guang-Han ;

Ren, Zhi .

PHYSICAL REVIEW MATERIALS, 2023, 7 (01)

[48] Synthesis and crystal structure of borate oxide Co3BO5 [J].

Zhang, H ;

Cheng, WD ;

Huang, ZX .

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2001, 20 (02) :97-99

[49] Crystal structure of 5-hydroxy-5-propylbarbituric acid [J].

Gelbrich, Thomas ;

Griesser, Ulrich J. .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 :1311-+

[50] Substitution of W5+ in monophosphate tungsten bronzes by combinations Mn+/W6+ [J].

Roy, Subrata Chandra ;

Assenmacher, Wilfried ;

Linden, Thomas ;

Esser, Lars ;

Mader, Werner ;

Glaum, Robert .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2016, 71 (05) :543-552

← 1 2 3 4 5 →