Crystal structure of (OC)(5)W(mu-dppe) W(CO)(5)

被引:0
作者
Drake, Hannah F. [1 ]
Wheeler, Kraig A. [2 ]
Bellott, Brian J. [1 ]
机构
[1] Western Illinois Univ, Dept Chem, Macomb, IL 61455 USA
[2] Eastern Illinois Univ, Dept Chem, Charleston, IL 61920 USA
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷
基金
美国国家科学基金会;
关键词
crystal structure; group; 6; carbonyl; bridging dppe; bimetallic;
D O I
10.1107/S2056989016013670
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The centrosymmetric title complex, [mu-ethane-1,2-diylbis(diphenylphosphane)-kappa P-2: P '] bis[pentacarbonyltungsten(0)], [W2(C26H24P2)(CO) 10], consists of two W(CO)(5) moieties bridged by a bis(diphenylphosphanyl) ethane (dppe) ligand. The W-0 atom has a slightly distorted octahedral coordination environment consisting of 5 carbonyl ligands and one P atom from the bridging dppe ligand with the nearest W-0 atom 5.625 (5) angstrom away. The complex resides on a center of symmetry.
引用
收藏
页码:1383 / +
页数:8
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