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Crystal structure of (OC)(5)W(mu-dppe) W(CO)(5)
被引:0
作者:
Drake, Hannah F.
[1
]
Wheeler, Kraig A.
[2
]
Bellott, Brian J.
[1
]
机构:
[1] Western Illinois Univ, Dept Chem, Macomb, IL 61455 USA
[2] Eastern Illinois Univ, Dept Chem, Charleston, IL 61920 USA
来源:
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
|
2016年
/
72卷
基金:
美国国家科学基金会;
关键词:
crystal structure;
group;
6;
carbonyl;
bridging dppe;
bimetallic;
D O I:
10.1107/S2056989016013670
中图分类号:
O7 [晶体学];
学科分类号:
0702 ;
070205 ;
0703 ;
080501 ;
摘要:
The centrosymmetric title complex, [mu-ethane-1,2-diylbis(diphenylphosphane)-kappa P-2: P '] bis[pentacarbonyltungsten(0)], [W2(C26H24P2)(CO) 10], consists of two W(CO)(5) moieties bridged by a bis(diphenylphosphanyl) ethane (dppe) ligand. The W-0 atom has a slightly distorted octahedral coordination environment consisting of 5 carbonyl ligands and one P atom from the bridging dppe ligand with the nearest W-0 atom 5.625 (5) angstrom away. The complex resides on a center of symmetry.
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页码:1383 / +
页数:8
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