Crystal structure of (OC)(5)W(mu-dppe) W(CO)(5)

被引：0

作者：

Drake, Hannah F. ^{[1
]}

Wheeler, Kraig A. ^{[2
]}

Bellott, Brian J. ^{[1
]}

机构：

[1] Western Illinois Univ, Dept Chem, Macomb, IL 61455 USA

[2] Eastern Illinois Univ, Dept Chem, Charleston, IL 61920 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷

基金：

美国国家科学基金会;

关键词：

crystal structure; group; 6; carbonyl; bridging dppe; bimetallic;

D O I：

10.1107/S2056989016013670

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The centrosymmetric title complex, [mu-ethane-1,2-diylbis(diphenylphosphane)-kappa P-2: P '] bis[pentacarbonyltungsten(0)], [W2(C26H24P2)(CO) 10], consists of two W(CO)(5) moieties bridged by a bis(diphenylphosphanyl) ethane (dppe) ligand. The W-0 atom has a slightly distorted octahedral coordination environment consisting of 5 carbonyl ligands and one P atom from the bridging dppe ligand with the nearest W-0 atom 5.625 (5) angstrom away. The complex resides on a center of symmetry.

引用

页码：1383 / +

页数：8

共 50 条

[11] Synthesis and characterization of the linear M-Hg-M trimetallic complexes [eta(5)-Bz(5)C(5)(CO)(3)M](2)Hg and [eta(5)-HO2CC5H4(CO)(3)M](2)Hg (M=Cr, Mo, W). The X-ray crystal structure of [eta(5)-Bz(5)C(5)(CO)(3)W](2)Hg [J].

Song, LC ;

Zhang, LY ;

Tao, ZF ;

Hu, QM ;

Huang, XY .

POLYHEDRON, 1997, 16 (03) :403-408

[12] Synthesis and characterization of W=W doubly-bonded dimers [η5-RC5H4W(CO)(μ-SPh)]2 and [η5-RC5H4W(μ-Se)(μ-SPh)]2 (R=MeO2C, EtO2C).: Crystal and molecular structure of trans/syn-[η5-EtO2CC5H4W(μ-Se)(μ-SPh)]2 [J].

Song, LC ;

Wang, JQ ;

Hu, QM ;

Huang, XY .

JOURNAL OF COORDINATION CHEMISTRY, 1999, 46 (03) :245-255

[13] Mixed-metal cluster chemistry .5. Syntheses and x-ray crystal structure of Cp2Mo2Ir2(mu(3)-CO)(mu-CO)(5)(CO)(4) [J].

Lucas, NT ;

Humphrey, MG ;

Hockless, DCR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 535 (1-2) :175-181

[14] PHOTOCHEMICAL-REACTION OF W(CO)(6) WITH SNCL4 .1. SYNTHESIS AND X-RAY STRUCTURE OF TRI-MU-CHLORO-TRICHLOROSTANNATE-HEPTACARBONYLDITUNGSTEN(II) [(CO)(4)W(MU-CL)(3)W(SNCL3)(CO)(3)] [J].

SZYMANSKA-BUZAR, T ;

GLOWIAK, T .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 489 (1-2) :207-214

[15] Reactions of diferrocenyl dichalcogenides with [W(CO)5(THF)]:: X-ray crystal structures of Fc2Te2 and [W2(μ-SeFc)2(CO)8] (Fc=[Fe(η5-C5H5)(η5-C5H4)]) [J].

Burgess, Mark R. ;

Jing, Su ;

Morley, Christopher P. ;

Thone, Carsten .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (23) :4963-4967

[16] SYNTHESIS OF THE STERICALLY HINDERED COMPLEXES [M(CO)5(CNBR2)] [R=CH(SIME3)2, M=CR, MO, OR W] - CRYSTAL-STRUCTURE OF [CR(CO)5(CNBR2)] [J].

BECK, G ;

LAPPERT, MF ;

HITCHCOCK, PB .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 468 (1-2) :143-148

[17] Synthesis and crystal structure of (CO)5ReSnMe2Re(CO)5 [J].

Li, J ;

Liu, H ;

Song, XQ ;

Kai, L ;

Yin, N .

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 1999, 18 (02) :114-118

[18] Reactions of SmI2(THF)(x) with [Cp'Mo(CO)(3)]Hg-2(Cp'=C5H5- or C(5)Me(5)(-)): Crystal and molecular structures of [(THF)(4)I2Sm(mu-OC)Mo(CO)(2)(C5H5)] and [(C(5)Me(5))Mo(CO)(3)](2) [J].

Lin, GY ;

Wong, WT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 522 (02) :271-275

[19] THE PREPARATION OF THE MIXED THIOLATO ISOCYANIDE COMPLEXES CIS-(ETA(5)-C5H5)W(CO)2(SR)(CNR') AND TRANS-(ETA(5)-C5H5)W(CO)2(SR)(CNR') - THE STRUCTURE OF TRANS-(ETA(5)-C5H5)W(CO)2(S-4-C6H4ME)(CNCME3) [J].

SHAVER, A ;

HYNES, RC ;

TROJANSEK, D .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 483 (1-2) :1-5

[20] Photochemical reaction of W(CO)(6) with SnCl4 .4. Synthesis of new tungsten alkyne complexes: X-ray crystal structure of [W-3(mu(3)-O)(mu-OH)(2)(mu-Cl)(2)(O)(eta(2)-PhC CPh)(5)] [J].

Szymanska-Buzar, T ;

Glowiak, T .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 523 (01) :63-74

← 1 2 3 4 5 →