Crystal structure of (OC)(5)W(mu-dppe) W(CO)(5)

被引：0

作者：

Drake, Hannah F. ^{[1
]}

Wheeler, Kraig A. ^{[2
]}

Bellott, Brian J. ^{[1
]}

机构：

[1] Western Illinois Univ, Dept Chem, Macomb, IL 61455 USA

[2] Eastern Illinois Univ, Dept Chem, Charleston, IL 61920 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2016年 / 72卷

基金：

美国国家科学基金会;

关键词：

crystal structure; group; 6; carbonyl; bridging dppe; bimetallic;

D O I：

10.1107/S2056989016013670

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The centrosymmetric title complex, [mu-ethane-1,2-diylbis(diphenylphosphane)-kappa P-2: P '] bis[pentacarbonyltungsten(0)], [W2(C26H24P2)(CO) 10], consists of two W(CO)(5) moieties bridged by a bis(diphenylphosphanyl) ethane (dppe) ligand. The W-0 atom has a slightly distorted octahedral coordination environment consisting of 5 carbonyl ligands and one P atom from the bridging dppe ligand with the nearest W-0 atom 5.625 (5) angstrom away. The complex resides on a center of symmetry.

引用

页码：1383 / +

页数：8

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