IONIC CONDUCTIVITY OF LEAD CHLORIDE CRYSTALS

被引：34

作者：

HOSHINO, H

YAMAZAKI, M

NAKAMURA, Y

SHIMOJI, M

机构：

[1] Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo

来源：

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN | 1969年 / 26卷 / 06期

关键词：

D O I：

10.1143/JPSJ.26.1422

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The ionic conductivity of single crystals of pure and KCl- and NaCl-doped PbCl2 has been measured between 90 and 400°C. The thermal disorder appears to be of unassociated Schottky defects. The expressions for the “mobility” μ and the “concentration” xn0 of anion vacancies have been determined from a comparison between the observed isothermals and those predicted from the simple theory of Koch and Wagner in which association effects are omitted. The experimental expressions are [formula omitted] and [formula omitted] in mole fraction, where kT is expressed in electron-volt. These are the first results, expressed as a function of temperature, for anion vacancies in PbCl2 crystals. © 1969, THE PHYSICAL SOCIETY OF JAPAN. All rights reserved.

引用

页码：1422 / &

共 18 条

[1] LATTICE DISORDER IN SOME CAF2-TYPE CRYSTALS [J].