PVT DATA-ANALYSIS USING NEURAL-NETWORK MODELS

被引:43
作者
NORMANDIN, A [1 ]
GRANDJEAN, BPA [1 ]
THIBAULT, J [1 ]
机构
[1] LAVAL UNIV,DEPT CHEM ENGN,ST FOY G1K 7P4,PQ,CANADA
关键词
D O I
10.1021/ie00017a029
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
PVT data analysis is performed for pure gases and vapors using neural network based models. The resulting equations of state (EOS) are explicit forms of the compressibility factor as a function of the reduced temperature and pressure, and the acentric factor. In order to represent the whole domain of pressure and temperature, two EOS have been developed, one equation specifically covering the critical region. These two equations were obtained by fitting a large number of experimental data points (about 1000 and 1500, respectively) characterizing the behavior of several pure components (5 and 8, respectively). The EOS have been applied successfully to various other components and were found to give accurate predictions for a reduced pressure as high as 10. Derivation of the fugacity coefficient is also presented.
引用
收藏
页码:970 / 975
页数:6
相关论文
共 29 条
[1]  
ANGUS S, 1979, INT THERMODYNAMIC TA, V6
[2]  
ANGUS S, 1980, INT THERMODYNAMIC TA, V7
[3]  
BELZILE JL, 1976, THESIS U LAVAL QUEBE
[4]  
BHAGAT P, 1990, CHEM ENG PROG, V86, P55
[5]   USE OF NEURAL NETS FOR DYNAMIC MODELING AND CONTROL OF CHEMICAL PROCESS SYSTEMS [J].
BHAT, N ;
MCAVOY, TJ .
COMPUTERS & CHEMICAL ENGINEERING, 1990, 14 (4-5) :573-583
[6]  
CAUDILL M, 1990, AI EXPERT, P43
[7]  
DAS TR, 1977, J CHEM ENG DATA, V22, P3, DOI 10.1021/je60072a014
[8]   FAULT-DIAGNOSIS IN COMPLEX CHEMICAL-PLANTS USING ARTIFICIAL NEURAL NETWORKS [J].
HOSKINS, JC ;
KALIYUR, KM ;
HIMMELBLAU, DM .
AICHE JOURNAL, 1991, 37 (01) :137-141
[9]  
Lippman R. P., 1987, IEEE ASSP MAGAZI APR, P4
[10]   PHYSICAL AND THERMODYNAMIC PROPERTIES OF 1,1,2-TRIFLUOROTRICHLOROETHANE (R-113) [J].
MASTROIANNI, MJ ;
STAHL, RF ;
SHELDON, PN .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1978, 23 (02) :113-118