ELECTROSTATIC-FIELD OF CHARGE-DISTRIBUTIONS ENCLOSED IN A POLARIZABLE MEDIUM - SOLVENT EFFECTS IN ELECTRONIC-SPECTRA OF KETYL ION-PAIRS

被引：1

作者：

MCCLELLAND, BJ ^{[1
]}

MODINOS, A ^{[1
]}

机构：

[1] NATL TECH UNIV ATHENS,DEPT PHYS,GR-15773 ATHENS,GREECE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1991年 / 87卷 / 08期

关键词：

D O I：

10.1039/ft9918701117

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Explicit formulae are derived for the electrostatic field, and quantities associated with it, of an arbitrary system of point charges contained in two spherical cavities in a uniform dielectric medium; the mathematical technique is borrowed from multiple-scattering theory. This system is considered as a model for polyatomic ion pairs in solution. The formulae are applied to the alkali-metal-benzophenone contact ion pairs, and it is shown that experimentally observed solvent shifts and cation-radius dependence of the absorption band maximum at ca. 650 nm are thereby explained.

引用

页码：1117 / 1126

页数：10