CARBONIUM ION FORMATION IN SOLVOLYSIS OF PHOSPHATE TRIESTERS

被引：20

作者：

COX, JR

NEWTON, MG

机构：

[1] School of Chemistry, Institute of Technology, Atlanta

[2] Department of Chemistry, University of Houston, Houston

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 09期

关键词：

D O I：

10.1021/jo01261a025

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The mechanisms of solvolysis of some triesters of phosphoric acid which might form carbonium ions have been investigated. Such a pathway is shown to be predominant in the solvolysis of tri-t-butyl and triisopropyl phosphates, but to be negligible in the case of triallyl phosphate. The solvolytic behavior of some five-membered cyclic tertiary alkyl esters is briefly discussed. © 1969, American Chemical Society. All rights reserved.

引用

页码：2600 / &

共 18 条

[1]

ANBAR M, 1959, INT J APPL RADIAT IS, V4, P233

[2]

ARBUZOV AE, 1949, IAN SSSR KH, P473

[3] REACTIONS OF ORGANIC PHOSPHATES .5. HYDROLYSIS OF TRIPHENYL AND TRIMETHYL PHOSPHATES [J].