Tetrachloridodi-mu(3)-oxido-tetrakis(mu(2)-propan-2-olato-kappa O-2:O)ditin(II)ditin(IV)

被引：0
作者：
Yarushnikov, Oleg [1 ]
Naumova, Dina [1 ]
Klishin, Nikolai [1 ]
Rusanov, Eduard [2 ]
Brusylovets, Oleksii [1 ]
机构：
[1] Kiev Natl Taras Shevchenko Univ, Dept Chem, Volody Myrska St 64, UA-01601 Kiev, Ukraine
[2] Inst Organ Chem, UA-253660 Kiev, Ukraine
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
data-to-parameter ratio = 32.7; mean σ(C-C) = 0.008 Å; R factor = 0.038; single-crystal X-ray study; T = 296 K; wR factor = 0.061;
D O I：
10.1107/S1600536814000816
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The centrosymmetric tetranuclear title molecule, [Sn-4-(C3H7O)(4)Cl4O2], contains two types of Sn atoms, Sn-II and Sn-IV. The SnII atom has a trigonal-pyramidal coordination environment and is bonded to two O atoms from two isopropanolate groups and one mu(3)-oxide atom. The Sn-IV atom has an octahedral coordination environment, formed by two chloride atoms, two mu(3)-oxide atoms and two O atoms from isopropanolate groups.
引用
收藏
页码：M45 / +
页数：8
相关论文
共 12 条
  • [1] Hydrolysis of in(II) neo-pentoxide:: Syntheses, characterization, and X-ray structures of [Sn(ONeP)2]∞, Sn5(μ3-O)2(μ-ONeP)6, and Sn6(μ3-O)4(μ-ONeP)4 where ONeP = OCH2CMe3
    Boyle, TJ
    Alam, TM
    Rodriguez, MA
    Zechmann, CA
    [J]. INORGANIC CHEMISTRY, 2002, 41 (09) : 2574 - 2582
  • [2] SIR2004:: an improved tool for crystal structure determination and refinement
    Burla, MC
    Caliandro, R
    Camalli, M
    Carrozzini, B
    Cascarano, GL
    De Caro, L
    Giacovazzo, C
    Polidori, G
    Spagna, R
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2005, 38 : 381 - 388
  • [3] Single-Source Materials for Metal-Doped Titanium Oxide: Syntheses, Structures, and Properties of a Series of Heterometallic Transition-Metal Titanium Oxo Cages
    Eslava, Salvador
    McPartlin, Mary
    Thomson, Richard I.
    Rawson, Jeremy M.
    Wright, Dominic S.
    [J]. INORGANIC CHEMISTRY, 2010, 49 (24) : 11532 - 11540
  • [4] WinGX and ORTEP for Windows: an update
    Farrugia, Louis J.
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2012, 45 : 849 - 854
  • [5] Reactions of chlorotitanium tri-iso-propoxide with methanol and tributylamine
    Fric, Helmut
    Schubert, Ulrich
    [J]. JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2008, 48 (1-2) : 2 - 5
  • [6] Harrison P. G., 1978, CHEM COMMUN, P112
  • [7] Mijatovic I, 2001, EUR J INORG CHEM, P1933
  • [8] SYNTHESIS AND CHARACTERIZATION OF DIORGANOTIN DIETHYLPHOSPHOROTHIOATES - CRYSTAL-STRUCTURES OF ([ME2SN(O(S)P(OET)2)]2O)2 AND [TBU2SN(MU-OH)(O(S)P(OET)2)]2
    MOKAL, VB
    JAIN, VK
    TIEKINK, ERT
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 471 (1-2) : 53 - 61
  • [9] Processing of X-ray diffraction data collected in oscillation mode
    Otwinowski, Z
    Minor, W
    [J]. MACROMOLECULAR CRYSTALLOGRAPHY, PT A, 1997, 276 : 307 - 326
  • [10] A short history of SHELX
    Sheldrick, George M.
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
12