SYNTHESIS OF VOLATILE, FLUORINATED BETA-KETOIMINATO COPPER(I) COMPLEXES

被引：31

作者：

SHIN, HK

HAMPDENSMITH, MJ

KODAS, TT

RHEINGOLD, AL

机构：

[1] UNIV NEW MEXICO,DEPT CHEM,ALBUQUERQUE,NM 87131

[2] UNIV NEW MEXICO,CTR MICROENGINEERED CERAM,ALBUQUERQUE,NM 87131

[3] UNIV NEW MEXICO,DEPT CHEM ENGN,ALBUQUERQUE,NM 87131

[4] UNIV DELAWARE,DEPT CHEM,NEWARK,DE 19716

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 03期

关键词：

D O I：

10.1039/c39920000217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The fluorinated beta-ketoimines, 4-(alkyl)imino-1,1,1,5,5,5-hexafluoropentan-2-one, where alkyl = isopropyl 3 or trifluoroethyl 6, have been obtained in high yield from the reaction of a silyl ether of hexafluoroacetylacetone with isopropylamine and trifluoroethylamine, respectively, and used to prepare volatile, monomeric copper(I) beta-ketoiminate complexes.

引用

页码：217 / 219

页数：3

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