CRYSTAL-STRUCTURE OF A NOVEL MIXED-VALENCE MOV-MOVI HETEROPOLYMOLYBDATE CLUSTER - [H3O+]6 [MO57V6O183(NO)6(H2O)18]6-.89H2O

被引：44
作者：
ZHANG, SW
HUANG, GQ
SHAO, MC
TANG, YQ
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 01期
关键词：
D O I：
10.1039/c39930000037
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of sodium molybdate (Na2MoO4.2H2O) and ammonium metavanadate (NH4VO3) with hydroxylamine hydrochloride results in the formation of the title compound, which consists of three 19-molybdate subunits being connected by six VO6 octahedra, and six bridging water molecules; both the manner of linking of the VO6 octahedra to the 19-molybdate subunit and the formation of a polymetallate cluster containing 57 discrete Mo atoms, are hitherto unknown features.
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页码：37 / 38
页数：2
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